Immobilization of Metal Nanoparticles to an Ultrathin Two-Dimensional Conjugated Metal-Organic Framework for Synergistic Electrocatalysis.

Metal-organic frameworks (MOFs) have been considered as promising hosts for immobilizing ultrafine metal nanoparticles (MNPs) due to their high surface area and porosity. However, electrochemical applications of such emerging composites are severely limited by the poor electrical conductivity and large size of the MOFs. Herein, we report the general synthesis of incorporating various MNPs into a conjugated MOF ultrathin nanosheet (Cu-TCPP UNS) matrix, which not only prevents agglomeration and restricts the growth of MNPs but also benefits the exposure of active sites and the transport of electrons. Specifically, the obtained PtCu@Cu-TCPP UNSs exhibited nearly two times higher mass activity for the methanol oxidation reaction (MOR) than the commercial Pt/C catalyst. Mechanistic studies reveal that the strong interaction between MNPs and Cu-TCPP promotes the oxidation of the CO intermediate. Moreover, the PtCu@Cu-TCPP UNSs can be employed as bifunctional electrocatalysts to couple MOR with the hydrogen evolution reaction for highly efficient hydrogen production.