We report an aniline ligand (1) with two (pyrazolyl)alkane arms, and its cationic, dizinc complexes. XRD, NMR, and modelling of the dizinc complexes resulted in an unprecedented, dynamic μ-anilide core. Compared with published μ-phenolate analogues, our μ-anilide complexes show higher activity and divergent counterion trends in ring-opening polymerization of -lactide.
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http://dx.doi.org/10.1039/d4dt02837f | DOI Listing |
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