Regulating the Electronic Structure of Cu Single-Atom Catalysts toward Enhanced Electro-Fenton Degradation of Organic Contaminants via O and OH.

Environ Sci Technol

Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China.

Published: October 2024

Heterogeneous electro-Fenton degradation with O and OH generated from O reduction is cost-effective for the removal of refractory organic pollutants from wastewater. As O is more tolerant to background constituents such as salt ions and a high pH value than OH, tuning the production of O and OH is important for efficient electro-Fenton degradation. However, it remains a great challenge to selectively produce O and improve the species yield. Herein, the electronic structure of atomically dispersed Cu-N sites was regulated by doping electron-deficient B into porous hollow carbon microspheres (CuBN-HCMs), which improved *O adsorption and significantly enhanced O selectivity in electro-Fenton degradation. Its O yield was 2.3 times higher than that of a Cu single-atom catalyst without B doping. Meanwhile, OH was simultaneously generated as a minor species. The CuBN-HCMs were efficient for the electro-Fenton degradation of phenol, sulfamethoxazole, and bisphenol A with a high mineralization efficiency. Its kinetic constants showed insignificant changes under various anions and a wide pH range of 1-9. More importantly, it was energy-efficient for treating actual coking wastewater with a low energy consumption of 19.0 kWh kg. The superior performance of the CuBN-HCMs was contributed from O and OH and its high O selectivity.

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Source
http://dx.doi.org/10.1021/acs.est.4c08704DOI Listing

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