Searching for lightweight and high-temperature stable electromagnetic wave-absorbing materials with broad absorbing bandwidth and high efficiency is of significance for applications in daily life and industry. Optimizing the dielectric properties of SiC nanowire aerogel by both compositional and structural designs is an efficient way to obtain simultaneous efficient wave-dissipation ability and good impendence matching and thus the desired properties. However, due to the complex effects of dielectric parameters on the wave-absorbing properties, rational design of high-performance electromagnetic wave-absorbing materials remains challenging. Herein, we propose a genetic algorithm-based approach to predict broadband and highly efficient electromagnetic wave-absorbing materials in a SiC@SiO nanowire aerogel-based system. The obtained SiC@SiO nanowire aerogels exhibit a gradient multilayered structure with a low dielectric outer layer, a medium layer with alternatively distributed electromagnetic wave transparent and attenuation layers, and an inner high attenuation layer, giving it a broadband electromagnetic wave-absorbing performance covering almost all the 2-18 GHz bandwidth and simultaneous high efficiency. The results show that the genetic algorithm-based approach is efficient in predicting high-performance electromagnetic wave-absorbing ceramic aerogels.
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http://dx.doi.org/10.1021/acsami.4c13946 | DOI Listing |
Carbohydr Polym
March 2025
Biofuels Institute, School of Environment and Safety Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China. Electronic address:
Due to the increasing pollution of electromagnetic waves and the vigorous development of intelligent electronic devices, there is great interest in finding high-quality electromagnetic wave absorbing materials for integrated control boxes (ICBs) that integrate various electronic components. Polyaniline (PANI) is a new type of absorbing material with great potential due to its designable structure, simple preparation process, low density and adjustable conductivity. Herein, we prepared BCNF/PANI nanoscale conductive fibers with core-shell structure by in-situ growth of PANI on the surface of bacterial cellulose nanofibers (BCNF) by oxidative polymerization and further prepared cellulose/polyaniline/polyvinyl alcohol (BCNF/PANI/PVA) composite aerogel absorbing material by a freeze-drying process.
View Article and Find Full Text PDFSmall
January 2025
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, P. R. China.
Electromagnetic pollution protection and military stealth technologies underscore the urgent need to develop efficient electromagnetic wave-absorbing materials (EWAMs). Traditional EWAMs suffer from single absorption loss mechanisms, poor impedance matching, and weak reflection loss. To date, combining dielectric loss with magnetic loss in EWAMs have proven to be an effective approach to enhancing electromagnetic absorption performance.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Key Laboratory of Bamboo Research of Zhejiang Province, Zhejiang Academy of Forestry, Hangzhou 310023, China.
Bamboo was carbonized and further modified via co-doping with graphene oxide (GO) and polyaniline (PANI) to prepare microwave absorption composites (GO/PANI/CB) by in situ polymerization of 1R-(-)-Camphorsulfonic acid (L-CSA). The conductivity of GO/PANI/CB reached 2.17 ± 0.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
School of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing 211167, China.
In this study, CO reacted with a curing agent through nucleophilic addition to form ammonium salts, enabling the stable capture and internal release of CO, which achieved gas-phase nucleation and foaming. Additionally, the introduction of wave-absorbing agents improved the absorption mechanism and promoted uniform foaming. This nucleation-free foaming process relies on the induced growth of gas nuclei and the synergistic effect of the wave-absorbing agents, effectively preventing the uneven foaming issues caused by traditional nucleating agents.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Institute of Corrosion Science and Technology, Guangzhou 510530, China.
With the development of science and technology, there is a great demand for electromagnetic wave absorbing materials for both military and civilian purposes. Among them, carbonyl iron powder (CIP) has attracted a lot of attention due to its mature production system and good electromagnetic wave loss capability. However, the application of CIP is limited due to poor impedance matching, poor corrosion resistance, and poor oxidation resistance.
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