Reactions of -carborane-fused diborane(4) with 3-diazirines led to the complete cleavage of the N[double bond, length as m-dash]N bond, with one nitrogen atom being incorporated into the B-B bond. The molecular and electronic structures of the resultant borylnitrogen compounds were confirmed through single-crystal X-ray analyses and computational studies. The related reaction mechanism was investigated using DFT calculations.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11474396 | PMC |
| http://dx.doi.org/10.1039/d4sc04980b | DOI Listing |
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