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Exploring Singlet Carbyne Anions and Related Low-Valent Carbon Species Utilizing a Cyclic Phosphino Substituent.
Acc Chem Res
January 2025
Department of Chemistry and Research Center for Chemical Biology and Omics Analysis, College of Science, Southern University of Science and Technology, Shenzhen 518055, China.
ConspectusThe advancement of synthetic methodologies is fundamentally driven by a deeper understanding of the structure-reactivity relationships of reactive key intermediates. Carbyne anions are compounds featuring a monovalent anionic carbon possessing four nonbonding valence electrons, which were historically confined to theoretical constructs or observed solely within the environment of gas-phase studies. These species possess potential for applications across diverse domains of synthetic chemistry and ancillary fields.
View Article and Find Full Text PDFA journey towards the pot of gold.
Brain
July 2023
Paris Brain Institute (ICM), INSERM U 1127, CNRS UMR 7225, Sorbonne University, Paris, France UMR 7225, Sorbonne University, Paris, France.
Microbiota and probiotics: chances and challenges - a symposium report.
Gut Microbiome (Camb)
March 2023
Yakult Europe BV, Almere, Netherlands.
The 10th International Yakult Symposium was held in Milan, Italy, on 13-14 October 2022. Two keynote lectures covered the crewed journey to space and its implications for the human microbiome, and how current regulatory systems can be adapted and updated to ensure the safety of microorganisms used as probiotics or food processing ingredients. The remaining lectures were split into sections entitled "Chances" and "Challenges.
View Article and Find Full Text PDFChanges of Cadmium Storage Forms and Isotope Ratios in Rice During Grain Filling.
Front Plant Sci
April 2021
ISTerre, Université Grenoble Alpes, Université Savoie Mont Blanc, Centre National de la Recherche Scientifique, Institut de Recherche pour le Développement, Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux, Grenoble, France.
Rice poses a major source of the toxic contaminant cadmium (Cd) for humans. Here, we elucidated the role of Cd storage forms (i.e.
View Article and Find Full Text PDFNovel one pot synthesis and spectroscopic characterization of a folate-MnO nanohybrid for potential photodynamic therapeutic application.
RSC Adv
September 2019
Department of Chemical, Biological and Macromolecular Sciences, S. N. Bose National Centre for Basic Sciences Block JD, Sector 3, Salt Lake Kolkata-700106 India +91 33 2335 3477 +91 33 2335 5706/08.
Treatment of cancer using nanoparticles made of inorganic and metallic compounds has been increasingly used, owing to their novel intrinsic physical properties and their potential to interact with specific cellular sites, thereby significantly reducing severe secondary effects. In this study, we report a facile strategy for synthesis of folate capped MnO nanoparticles (FA-MnO NPs) with high colloidal stability in aqueous media using a hydrothermal method for potential application in photodynamic therapy (PDT) of cancer. The capping of FA to MnO NPs was confirmed using various spectroscopic techniques.
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