Eradicating the Photogenerated Holes in a Photocatalyst-Microbe Hybrid System: A Review.

Finding advanced technologies to store solar energy in chemical bonds efficiently is of great significance for the sustainable development of our society. The recently reported photocatalyst-microbe hybrid (PMH) system couples photocatalysts intimately with microbes and endows heterotrophic microbes with light-harvesting capacity. Generally, when PMH systems are exposed to light, photocatalytic reactions occur on the surface of photocatalysts and the photogenerated electrons enter microbial cells to promote the generation of energy carriers (such as nicotinamide adenine dinucleotide phosphate hydrogen and adenosine triphosphate) and the following chemical synthesis. PMH system applications have expanded from synthesizing value-added products (chemicals, fuels, and polymers) to treating pollutants. However, the successful operation of the PMH system relies on the timely eradication of the photogenerated holes as they recombine with the photogenerated electrons and cause the photocorrosion of the photocatalyst. This review summarizes the strategies for scavenging the photogenerated holes in PMH systems and provides insight into the current gaps and outlooks for future opportunities in this field.