A 2-fold interpenetrating 3D pillar-layered MOF, which was assembled from a mixed-linker and paddle-wheel cluster, was successfully synthesized. It possesses good thermal and water stability as well as high selectivity for CH over CH and CO over N under ambient conditions, which was further proved by breakthrough experiments. Moreover, this porous material exhibits good detection of Cu, [Co(NH)] and Fe in an aqueous solution.

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http://dx.doi.org/10.1039/d4dt02024cDOI Listing

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