Ultracold atoms exquisitely controlled by lasers are the quantum foundation, particularly for sensing, timekeeping, and computing, of state-of-the-art quantum science and technology. However, the laboratory-scale infrastructure for such optical-atomic quantum apparatus rarely translates into commercial applications. A promising solution is miniaturizing the optical layouts onto a chip-scale device integrated with cold atoms inside a compact ultra-high vacuum (UHV) chamber. For prototyping purposes, however, rapidly loading or exchanging test photonic devices into a UHV chamber is limited by the evacuation time from atmospheric pressures to the optimal pressures for ultracold atoms of 1 × 10-11 Torr, a process that typically takes weeks or months without cryogenics. Here, we present a loadlock apparatus and loading procedure capable of venting, exchanging, and evacuating back to <1×10-11 Torr in under 24 h. Our system allows for rapid testing and benchmarking of various photonic devices with ultracold atoms.
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http://dx.doi.org/10.1063/5.0231241 | DOI Listing |
J Phys Chem A
November 2024
Copenhagen Center for Atmospheric Research, Department of Chemistry, University of Copenhagen, Universitetsparken 5, Frederiksberg, Copenhagen Ø DK-2100, Denmark.
Smog chamber experiments were conducted to establish the atmospheric chemistry of ()- and ()-CFCFCH═CHCFCF. Kinetics of the reactions of the two compounds with Cl atoms and OH radicals were measured using relative rate techniques, giving (Cl + ()-CFCFCH═CHCFCF) = (5.63 ± 0.
View Article and Find Full Text PDFRev Sci Instrum
October 2024
Department of Physics, University of California San Diego, San Diego, California 92093, USA.
Ultracold atoms exquisitely controlled by lasers are the quantum foundation, particularly for sensing, timekeeping, and computing, of state-of-the-art quantum science and technology. However, the laboratory-scale infrastructure for such optical-atomic quantum apparatus rarely translates into commercial applications. A promising solution is miniaturizing the optical layouts onto a chip-scale device integrated with cold atoms inside a compact ultra-high vacuum (UHV) chamber.
View Article and Find Full Text PDFJ Phys Chem A
September 2024
C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, West Virginia 26506, United States.
We investigated the reactions of the hydroxyl radical (OH) with cyclopentenone derivatives and cyclopentanone in a quasi-static reaction cell at 4 Torr across a 300-500 K temperature range. The OH radicals were generated using pulsed laser photolysis of hydrogen peroxide vapors, and the ketone reactants were introduced in excess. The relative concentrations of the radicals were monitored as a function of reaction time using laser-induced fluorescence.
View Article and Find Full Text PDFJ Phys Chem A
June 2024
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Criegee intermediates exert a crucial influence on atmospheric chemistry, functioning as powerful oxidants that facilitate the degradation of pollutants, and understanding their reaction kinetics is essential for accurate atmospheric modeling. In this study, the kinetics of CHOO and -CHCHOO reactions with acetaldehyde (CHCHO) were investigated using a flash photolysis reaction tube coupled with the OH laser-induced fluorescence (LIF) method. The experimental results indicate that the reaction of -CHCHOO with CHCHO is independent of pressure in the range of 5-50 Torr when using Ar as the bath gas.
View Article and Find Full Text PDFJ Mol Model
May 2024
School of Chemistry and Life Sciences, Hanoi University of Science and Technology, Hanoi, Vietnam.
Context: An ab initio investigation into the potential energy landscape of the meta-aminotoluene + OH reaction has been conducted in this study. The calculated results reveal that the reaction channel leading to the product (NHCHCH + HO) prevails under the 300-1700 K temperature range, while the reaction path forming the product (NHCHCH + HO) dominates in the higher-temperature region (T ≥ 1800 K). Within the specified temperature range, the product branching ratio for the former declines from 48 to 30%, while the latter shows an increase, reaching 29%.
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