Owing to the low potential (vs K/K), good cycling stability, and sustainability, carbon-based materials stand out as one of the optimal anode materials for potassium-ion batteries (PIBs). However, achieving high-rate performance and excellent capacity with the current carbon-based materials is challenging because of the sluggish reaction kinetics and the low capacity of carbon-based anodes. The doping of nitrogen proves to be an effective way to improve the rate performance and capacity of carbon-based materials as PIB anode. However, a review article is lacking in systematically summarizing the features and functions of nitrogen doping types. In this sense, it is necessary to provide a fundamental understanding of doped nitrogen types in nitrogen-doped(N-doped) carbon materials. The types, functions, and applications of nitrogen-doped carbon-based materials are overviewed in this review. Then, the recent advances in the synthesis, properties, and applications of N-doped carbon as both active and modification materials for PIBs anode are summarized. Finally, doped nitrogen's main features and functions are concluded, and critical perspectives for future research in this field are outlined.
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Sci Rep
December 2024
ICAR-Indian Grassland and Fodder Research Institute, Jhansi, 284 003, India.
Sugarcane is a major industrial crop highly susceptible to parasitic weed (Striga spp.), causing a 38% reduction in cane yield due to a longer lag phase of 20-40 days, and wider spacing. Herbicides with a longer retention and slow-release nature could allow Striga seeds to germinate and be killed before attaching to the host.
View Article and Find Full Text PDFEnviron Res
December 2024
School of Mechanical Science and Engineering, Northeast Petroleum University, Daqing 163318, China.
Porous carbon adsorption represents a critical component of CCUS technologies, with microporous structures playing an essential role in CO capture. The preparation of porous carbon introduces intrinsic defects, making it essential to consider both pore size and these defects for a comprehensive understanding of the CO adsorption mechanism. This study investigates the mechanisms of CO adsorption influenced by intrinsic defects and pore size using multiscale methods, incorporating experimental validation, Grand Canonical Monte Carlo simulations, and Density Functional Theory simulations.
View Article and Find Full Text PDFAdv Colloid Interface Sci
December 2024
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, China. Electronic address:
Catalytic species such as molecular catalysts and metal catalysts are commonly attached to varieties of supports to simplify their separation and recovery and accommodate various reaction conditions. The physicochemical microenvironments surrounding catalytic species play an important role in catalytic performance, and the rational design and engineering of microenvironments can achieve more efficient chemical synthesis, leading to greener and more sustainable catalysis. In this review, we highlight recent works addressing the topic of the design and engineering of microenvironments of supported catalysts, including supported molecular catalysts and supported metal catalysts.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
Departament de Ciència de Materials i Química Física, Institut de Química Teòrica i Computacional (IQTCUB), Universitat de Barcelona, C/Martí i Franquès 1-11, 08028 Barcelona, Spain.
The separation of oxygen (O) and nitrogen (N) from air is a process of utmost importance nowadays, as both species are vital for numerous fundamental processes essential for our development. Membranes designed for their selective molecule separation have become the materials of choice for researchers, primarily due to their ease of use. The present study proposes grazynes, 2D carbon-based materials consisting of and C atoms, as suitable membranes for separating O and N from air.
View Article and Find Full Text PDFBiosensors (Basel)
November 2024
Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences, Ningbo 315201, China.
This review examines recent advances in surface-enhanced Raman spectroscopy (SERS) for urinary metabolite analysis, focusing on the development and application of noble metal nanohybrids. We explore the diverse range of hybrid materials, including carbon-based, metal-organic-framework (MOF), silicon-based, semiconductor, and polymer-based systems, which have significantly improved SERS performance for detecting key urinary biomarkers. The principles underlying SERS enhancement in these nanohybrids are discussed, elucidating both electromagnetic and chemical enhancement mechanisms.
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