Discontinuity-enhanced icephobic surfaces for low ice adhesion.

J Colloid Interface Sci

Laboratory of Surface Engineering and Fluid Interfaces, Department of Materials Science, University of Milano-Bicocca, Milano 20125, Italy. Electronic address:

Published: February 2025

AI Article Synopsis

  • The research explores the design of ice-repellent surfaces using a combination of soft and rigid materials to improve durability while enhancing ice detachment mechanisms.
  • By fabricating model surfaces with varying rigid-soft ratios and discontinuity lengths, the study measures ice adhesion and analyzes how ice interacts with these surfaces through both experimental and numerical methods.
  • Key findings reveal that stress concentration at the edges of rigid-soft interfaces leads to effective crack propagation, promoting ice detachment and reducing adhesion, highlighting the role of discontinuities in this process.

Article Abstract

Hypothesis: Passive low ice-adhesion surfaces are frequently composed of soft materials; however, soft materials potentially present durability issues, which could be overcome by fabricating composite surfaces with patterned rigid and soft areas. Here we propose the innovative concept of discontinuity-enhanced icephobic surfaces, where the stress concentration at the edge between rigid and soft areas, i.e. where discontinuities in elasticity are located, facilitates ice detachment.

Experiments: Composite model surfaces were fabricated with controlled rigid-soft ratios and discontinuity line lengths. The ice adhesion values were measured while recording the ice/substrate interface, to unravel the underpinning ice detachment mechanism. The experiments were complemented by numerical simulations that provided a better understanding of the ice detachment mechanism.

Findings: It was found that when a surface contains rigid and soft areas, stress is concentrated at the edge between soft and hard areas, i.e. at the discontinuity line, rather than all over the soft or rigid areas. An unexpected non-unidirectional crack propagation was observed for the first time and elucidated. When rigid and deformable materials are present, the crack occurs on the discontinuity line and propagates first on rigid and then on soft areas. Moreover, it was demonstrated that an increase in discontinuities promotes crack initiation and leads to a reduction of ice adhesion.

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http://dx.doi.org/10.1016/j.jcis.2024.09.205DOI Listing

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