We report the synthesis of cationic 2,6-bisiminopyridine organoaluminum complexes, [(BIP)AlR], as stable BAr or PF salts, and their reversible single-electron reduction into well-defined paramagnetic species, [(BIP·)AlR]. Four redox couples, [(BIP)AlR], have been fully characterized through structural, spectroscopic, electrochemical and computational techniques.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11483753 | PMC |
| http://dx.doi.org/10.1021/acs.inorgchem.4c02664 | DOI Listing |
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