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Dynamic Jahn-Teller effect in the strong spin-orbit coupling regime. | LitMetric

AI Article Synopsis

Article Abstract

Exotic quantum phases, arising from a complex interplay of charge, spin, lattice and orbital degrees of freedom, are of immense interest to a wide research community. A well-known example of such an entangled behavior is the Jahn-Teller effect, where the lifting of orbital degeneracy proceeds through lattice distortions. Here we demonstrate that a highly-symmetrical 5d double perovskite BaMgReO, comprising a 3D array of isolated ReO octahedra, represents a rare example of a dynamic Jahn-Teller system in the strong spin-orbit coupling regime. Thermodynamic and resonant inelastic x-ray scattering experiments, supported by quantum chemistry calculations, undoubtedly show that the Jahn-Teller instability leads to a ground-state doublet, resolving a long-standing puzzle in this family of compounds. The dynamic state of ReO octahedra persists down to the lowest temperatures, where a multipolar order sets in, allowing for investigations of the interplay between a dynamic JT effect and strongly correlated electron behavior.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11450152PMC
http://dx.doi.org/10.1038/s41467-024-52935-wDOI Listing

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