Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 143
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3098
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
Severity: Warning
Message: Attempt to read property "Count" on bool
Filename: helpers/my_audit_helper.php
Line Number: 3100
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3100
Function: _error_handler
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
(NHC) → E coordination interactions are being explored in many chemical species, including carbones and nitreones. (NHC) → S interactions are rare, but increasing attention is being paid to the compounds containing such interactions. The electron deficiency at the S centre is responsible for triggering electron donation from the NHC unit in (NHC) → SR systems. It is well known that the positive charge at the sulfur centre increases upon single oxidation and further increases upon double oxidation. This implies that (NHC) → S interactions may become explicit after -oxidation in the (NHC) → SR systems. To explore this hypothesis, we performed quantum chemical design and synthesis of (NHC) → SR, (NHC) → S(O)R, and (NHC) → S(O)R complexes in which the ligands are imidazol-2-ylidene derivatives. Eight derivatives of the (imidazol-2-ylidene) → SR systems were generated, and their sulfoxide and sulfone derivatives were obtained by oxidation using urea-HO and mCPBA, respectively. The crystal structures of three compounds belonging to a series were determined. A comparison of the geometric, energetic and electronic characteristics confirmed the hypothesis that the (NHC) → S coordination interaction becomes comparatively stronger with an increase in oxygen atoms at the sulfur centre.
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Source |
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http://dx.doi.org/10.1039/d4dt02286f | DOI Listing |
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