Readily synthesized bench-stable glycosyl dithioimidocarbonates are useful -glycoside precursors. Under mild photochemical conditions, these glycosides undergo desulfurative glycosyl radical generation in the presence of weak acid, 4CzIPN, and Hantzsch ester. These radicals perform well in Geise-like reactions to yield -glycosides with high stereoselectivity.
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| http://dx.doi.org/10.1021/acs.orglett.4c03035 | DOI Listing |
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