Latex-Bridged Inverse Pickering Emulsion for Durable Superhydrophobic Coatings with Dual Antibacterial Activity.

There is agreement that every colloidal structure produces its own set of unique characteristics, properties, and applications. A colloidal phenomenon of latex-bridged water in a dimethyl carbonate (DMC) Pickering emulsion stabilized by R202 hydrophobic silica was investigated for its ability to act as a superhydrophobic coating (SHC) for cellulose substrates. First, various emulsion compositions were screened for their stability and droplet size. The final composition was then cross-examined by cryogenic scanning electron microscopy and optical and fluorescent microscopy to verify the colloidal structure. The drying pattern of the coating was investigated by using labeled samples under a fluorescent microscope and by scanning electron microscopy on a paper substrate. After the final ∼3 μm of dry coating was applied, it exhibited superhydrophobicity (advancing contact angle = 155°) and full functionality after 5 min at room temperature (RT). Coated samples maintained superhydrophobicity after 20 abrasion cycles and mechanical integrity after 50 s of water immersion. The SHC-coated paper demonstrated compatibility with a standard laser printer, and the coated paper demonstrated superhydrophobicity after printing. Finally, a propolis/DMC extract was produced and then analyzed by gas chromatography-mass spectroscopy (GC-MS) and infused into the SHC (PSHC). The newly formed PSHC demonstrated its ability to act effectively against biofilm and planktonic cells and reduce their viability by over 90% and 99.99%, respectively.