Food additives enhance sensory pleasure and improve marketability in food product formulations, yet their potential health risks are highly consequential. Tertiary butylhydroquinone (TBHQ), in this regard, has a controversial reputation owing to its neurotoxic effects, which include convulsions and other chronic issues. This situation underscores the need for an advanced electrochemical sensing platform. The current study advocates the utilization of copper tungstate nanoparticles to enhance the sensitivity, selectivity, and efficiency in TBHQ detection, thus addressing the challenges posed by the excessive use of additives and safeguarding the integrity of the food supply chain. Hydrothermally synthesized CuWO nanoparticles exhibited superior physicochemical and morphological characteristics, bringing about wide linear response ranges (0.01 to 789 μM), high selectivity, excellent anti-interference capabilities, and a low detection limit of 0.9 nM (S/N = 3). The CuWO modified screen printed carbon electrode (SPCE) presents promising recovery ranges in food samples, facilitating real-time monitoring and streamlining the quality assessment of food additives.
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http://dx.doi.org/10.1016/j.foodchem.2024.141340 | DOI Listing |
Chromeno[4,3-]chromenes have shown potential as effective drugs against cardiovascular diseases. This study centered on a novel heterojunction nanocomposite TiO/CuWO, which incorporates titanium dioxide (TiO) and copper tungstate(vi) to improve photocatalytic efficiency. The characterization of the TiO/CuWO photocatalyst was performed using various techniques, including FT-IR, XRD, TEM, DRS, SEM, EDS, and XPS.
View Article and Find Full Text PDFDalton Trans
November 2024
Department of Ceramic Engineering, National Institute of Technology, Rourkela, Odisha, 769008, India.
This work integrates a unique porous carbon with a binary heterostructured NiFeO/CuWO composite to enhance electrocatalytic activity towards the oxygen evolution reaction. The NiFeO/CuWO binary heterostructure was prepared through the conventional co-precipitation method. The porous carbon with turbostratic order was obtained by the selective etching of SiO nanodomains from preceramic polymer-derived SiOC.
View Article and Find Full Text PDFPhys Chem Chem Phys
November 2024
School of Chemistry, University of Leeds, Leeds LS2 9JT, UK.
Copper tungstate (CuWO) has attracted significant attention over the past two decades. However, the adsorption of water onto CuWO, which plays a critical role in the photocatalytic water splitting process, has not been investigated in detail. In this study, we have employed density functional theory (DFT) calculations to investigate water adsorption onto the CuWO pristine (010) and reduced (101) surfaces.
View Article and Find Full Text PDFFood Chem
January 2025
Department of Chemistry, Stella Maris College, Affiliated to the University of Madras, Chennai, Tamil Nadu 600086, India.. Electronic address:
Appl Spectrosc
June 2024
Laser Research Center, Vilnius University, LT, Vilnius, Lithuania.
In this work, we present studies on the effect of laser wavelengths on the laser-induced plasma characterization using a femtosecond (fs) ytterbium-doped potassium-gadolinium tungstate (Yb:KGW) laser. Plasma plumes of copper, steel, ceramics, and glass samples were induced using a multiple shot of 200 fs laser pulses with 1030 nm and 343 nm wavelengths at fixed laser fluence () and analyzed using the laser-induced breakdown spectroscopy (LIBS) technique. Time-resolved fs-LIBS measurements were performed on the same set of samples and under the same experimental conditions.
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