Given that methane (CH) and nitrogen (N) have similar properties, achieving high-purity enrichment of CH from nitrogen-rich low-grade gas is extremely challenging and is of great significance for sustainable development in energy and the environment. This paper reviews the research progress on carbon-based materials, zeolites, and MOFs as adsorbent materials for CH/N separation. It focuses on the relationship between the composition, pore size, surface chemistry of the adsorbents, CH/N selectivity, and CH adsorption capacity. The paper also highlights that controlling pore size and atomic-scale composition and optimizing these features for the best match are key directions for the development of new adsorbents. Additionally, it points out that MOFs, which combine the advantages of carbon-based adsorbents and zeolites, are likely to become the most promising adsorbent materials for efficient CH/N separation.
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http://dx.doi.org/10.3390/molecules29184404 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China.
Recent progress in inverted perovskite solar cells (IPSCs) mainly focused on NiO modification and perovskite (PVK) regulation to enhance efficiency and stability. However, most works address only monofunctional modifications, and identical molecules with the ability to simultaneously optimize NiO interface and perovskite bulk phase have been rarely reported. This work proposes a dual modification approach using 4-amino-3,5-dichlorobenzotrifluoride (DCTM) to optimize both NiO upper interfaces and reduction of bulk defects in perovskite.
View Article and Find Full Text PDFBMC Chem
January 2025
Petroleum Application Department, Egyptian Petroleum Research Institute (EPRI), Cairo, 11727, Egypt.
The depletion of fossil fuels and growing environmental concerns necessitate the exploration of renewable energy sources. Biodiesel, a promising alternative fuel derived from sustainable feedstock, has attracted considerable attention. This study investigates the catalytic esterification of oleic acid, a readily available fatty acid, with ethanol for biodiesel production using a novel heterogeneous catalyst, ZrO/AlO.
View Article and Find Full Text PDFGels
November 2024
School of Mechanical and Aerospace Engineering, Gyeongsang National University, Jinju 52828, Republic of Korea.
Adsorption heat pumps (AHPs) have garnered significant attention due to their efficient use of low-grade thermal energy, eco-friendly nature, and cost-effectiveness. However, a significant challenge lies in developing adsorbent materials that can achieve a high uptake capacity, rapid adsorption rates, and efficient reversible release of refrigerants, such as ammonia (NH). Herein, we developed and synthesized a novel salt-embedded covalent organic framework (COF) composite material designed for enhanced NH capture.
View Article and Find Full Text PDFAnimals (Basel)
December 2024
Equine Clinic Hochmoor, Ruthmannstr. 10, 48712 Gescher, Germany.
This literature review focuses on diagnostics of equine asthma (EA), possible influencing factors on diagnostic techniques and latest developments in diagnosing horses during EA remission or with subclinical disease. Routine EA diagnostics include a clinical examination of the respiratory system with percussion and auscultation including a rebreathing examination, and clinical pathology including white blood cells and arterial blood gas analysis. Subsequent diagnostics include bronchoscopy to evaluate the amount and viscosity of respiratory secretion, bronchoalveolar lavage, and the cytology of tracheal aspirates (TAs) and bronchoalveolar lavage fluid (BALF).
View Article and Find Full Text PDFFront Microbiol
November 2024
College of Chinese Medicine, Hunan University of Chinese Medicine, Changsha, China.
Background: Individuals with obesity often experience elevated blood lipid levels, leading to a chronic low-grade inflammatory state, exacerbating liver oxidative stress, and increasing the risk of various metabolic diseases. Recent evidence suggests that intestinal microbiota and short-chain fatty acids (SCFAs) play crucial roles in the development and progression of obesity. While the mechanisms by which Lingguizhugan decoction (LGZGD) intervenes in obesity by improving lipid metabolism, enhancing insulin sensitivity, and reducing inflammatory responses are well-documented, its potential in intestinal microbiota and SCFAs remains unclear.
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