Due to the similar physical and chemical properties of ilmenite and olivine, separating them is challenging. The flotation process, with the use of collectors, is an effective method. In this study, a ternary collector consisting of aluminum ion (III), benzohydroxamic acid (BHA), and sodium oleate (NaOL) was prepared for the flotation separation of ilmenite and olivine. Through micro-flotation experiments, molecular dynamics simulation (MD), density functional theory (DFT), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and time-of-flight secondary ion mass spectrometry (TOF-SIMS) analysis, the synergistic effect between the components of the ternary collector and the adsorption configuration on the surface of ilmenite was investigated. The results revealed that at pH = 8, Al (III), BHA, and NaOL could coordinate and adsorb effectively on the surface of ilmenite, enhancing its floatability for separation from olivine. The adsorption configuration differed from previous reports, showing a co-adsorption of multiple forms on the surface of ilmenite.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11434116 | PMC |
http://dx.doi.org/10.3390/molecules29184379 | DOI Listing |
Molecules
September 2024
Faculty of Land Resources Engineering, Kunming University of Science and Technology, Kunming 650093, China.
Phys Chem Miner
June 2024
Chemistry and Physics of Materials, University of Salzburg, Jakob-Haringer-Str. 2a, 5020 Salzburg, Austria.
Unlabelled: The heat of mixing of some petrological relevant substitutions (i.e., Mg-Al, Si-Al, Mg-Ti, Mg-Ca, and Mg-Fe) was investigated systematically in silicates, titanates, tungstates, carbonates, oxides, hydroxides, and sulphates by density functional theory calculations (e.
View Article and Find Full Text PDFJ Phys Chem B
November 2023
School of Mechanical and Materials Engineering, Washington State University, Pullman Washington 99164-2920, United States.
Lunar and Martian regoliths, containing feldspar, pyroxene, ilmenite, olivine, and aluminite minerals, are excellent sources of metals such as aluminum, sodium, magnesium, and iron. Ionic liquids (ILs), which are excellent solvents with extremely low vapor pressure and high electrochemical stability, can be potentially leveraged for extracting metals from regolith in an extra-terrestrial environment. A critical step in the solvation process, which determines the effectiveness of the IL solvent, is the formation of solvation shells around the metal cations.
View Article and Find Full Text PDFSci Adv
October 2023
Department of Earth and Environment, Florida International University, Miami, FL 33155, USA.
Classic lamellar clinopyroxene-ilmenite intergrowths (type 1) are extended to include discovery of olivine-ilmenite-perovskite-wüstite (type 2) and olivine-spinel-perovskite (type 3) xenoliths in kimberlites from Liberia. Low titanium solubilities in olivine, garnet, and pyroxene cannot account for exsolution-like relations. Because the oxides coexist with high-pressure perovskite-structured silicate minerals in diamond, a permissive conclusion is that type 1 to type 3 xenoliths are of super-deep origin.
View Article and Find Full Text PDFSci Bull (Beijing)
September 2023
State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China.
Mare basalts returned by the Chang'E-5 (CE5) mission extend the duration of lunar volcanism almost one billion years longer than previously dated. Recent studies demonstrated that the young volcanism was related neither to radiogenic heating nor to hydrous melting. These findings beg the question of how the young lunar volcanism happened.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!