The search for adsorbents that are non-toxic and low cost with a high adsorption capacity and excellent recyclability is a priority to determine the way to reduce the serious environmental impacts caused by the discharge of effluents loaded with heavy metals. Bacterial cellulose (BC) biomass has functional groups such as hydroxyl and carbonyl groups that play a crucial role in making this cellulose so efficient at removing contaminants present in water through cation exchange. This research aims to develop an experimental process for the adsorption, elution, and reuse of bacterial cellulose biomass in treating water contaminated with Cr (VI). SEM images and the kinetics behavior were analyzed with pseudo-first- and pseudo-second-order models together with isothermal analysis after each elution and reuse process. The adsorption behavior was in excellent agreement with the Langmuir model along with its elution and reuse; the adsorption capacity was up to 225 mg/g, adding all the elution processes. This study presents a novel approach to the preparation of biomass capable of retaining Cr (VI) with an excellent adsorption capacity and high stability. This method eliminates the need for chemical agents, which would otherwise be difficult to implement due to their costs. The viability of this approach for the field of industrial wastewater treatment is demonstrated.
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http://dx.doi.org/10.3390/polym16182605 | DOI Listing |
Anal Methods
January 2025
State Key Laboratory of Pollution Control and Resources Reuse, School of the Environment, Nanjing University, Nanjing 210023, China.
Dichloroacetic acid (DCAA), trichloroacetic acid (TCAA), and bromate (BrO) are disinfection byproducts (DBPs) formed during drinking water treatment and pose health risks. Rapid and reliable detection of these DBPs is essential for ensuring water safety. Non-suppressed ion chromatography (IC)-electrospray ionization mass spectrometry (IC-ESI-MS/MS) offers a promising approach for simultaneous analysis of organic haloacetic acids (HAAs) and inorganic oxyhalides, but previous methods using toxic methylamine can pose health risks.
View Article and Find Full Text PDFACS Omega
December 2024
Faculty of Science, Department of Chemistry, Ege University, İzmir 35100, Turkey.
A novel environmentally friendly adsorbent, poly(limonene--divinylbenzene--2-acrylamido-2-methyl-1-propanesulfonic acid, LIM--DVB--AMPS), was synthesized and applied for the adsorption of methylene blue from aqueous solutions in this study. The structure, morphology, and thermal stability of the green adsorbent were determined by the FTIR, SEM, TGA/DTA/DTG, and BET techniques, ζ potential, and elemental analysis. The efficiency of the adsorption process was improved with respect to several experimental conditions, viz.
View Article and Find Full Text PDFJ Pharm Biomed Anal
February 2025
BioCrom, Instituto de Química, Departamento de Química Orgânica, Universidade Federal Fluminense, Niterói 24020-141, Brazil. Electronic address:
J Chromatogr B Analyt Technol Biomed Life Sci
December 2024
Institute of Food Safety, Chinese Academy of Inspection and Quarantine, Beijing 100176, China; Key Laboratory of Food Quality and Safety, State Administration for Market Regulation, Beijing 100176, China. Electronic address:
Tadalafil analogs are often illegally added to dietary supplements such as herbal beverages, protein powders and tablet foods. Due to the complexity of the matrices, effective extraction of tadalafil analogs is the key to achieve accurate quantification. Therefore, it is of great significance to establish a rapid and effective method for the analytical determination of tadalafil analogs in complex matrices.
View Article and Find Full Text PDFPolymers (Basel)
September 2024
Faculty of Engineering and Basic Sciences, Fundación Universitaria los Libertadores, Bogotá 111221, Colombia.
The search for adsorbents that are non-toxic and low cost with a high adsorption capacity and excellent recyclability is a priority to determine the way to reduce the serious environmental impacts caused by the discharge of effluents loaded with heavy metals. Bacterial cellulose (BC) biomass has functional groups such as hydroxyl and carbonyl groups that play a crucial role in making this cellulose so efficient at removing contaminants present in water through cation exchange. This research aims to develop an experimental process for the adsorption, elution, and reuse of bacterial cellulose biomass in treating water contaminated with Cr (VI).
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