Tetraallylsilane can undergo either a mono or double rearrangement when treated with iodine (I). The extent of rearrangement depends on the equivalents of I used, where 1 equivalent gives high yields of mono-rearranged products and excess (e.g., 3 equivalents) causes double rearrangement to occur. This transformation can be applied to the synthesis of potentially valuable silicon-stereogenic organosilanes.
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| http://dx.doi.org/10.3390/ijms25189996 | DOI Listing |
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