Exploring the intrinsic mechanisms of rare-earth ions entering the crystal phase has great significance for finely tuning the luminescent properties of glass-ceramics. Using Er ions as a probe, X-ray diffraction was employed to precisely measure the crystallinity of SiO-PbF-ErO glass-ceramics synthesized under various heat treatment conditions, confirming the occurrence of a rapid crystallization process. Additionally, by combining Judd-Ofelt theory with comprehensive analyses of absorption and fluorescence spectra, we calculated the relative proportions of Er ions present in the crystal phase. We found that the crystallization process in the glass-ceramics and the incorporation of Er ions into the crystal phase did not occur synchronously. This discovery provides new theoretical foundations and practical guidance for understanding the mechanism of rare-earth ion incorporation into crystal phases, which is significant for the development of functional materials with specific luminescent properties.
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| http://dx.doi.org/10.3390/nano14181479 | DOI Listing |
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