Directed transportation and collection of liquids and bubbles play a vital role in the survival of ecosystems. Among them, the optical response control is widely used in the fields of microfluidic chips and chemical synthesis because of its high remote operation and fast response speed. However, due to poor light transmission, the development direction of traditional near-infrared (NIR) absorbing materials in the field of visualization is limited, and there are few reports of manufacturing an operating platform that can realize the directional movement of droplets/bubbles on a single platform. Here, a transparent photo-responsive PBFS platform is prepared for droplet and bubble manipulation by coating the etched glass substrate with Prussian blue (PB) nanocubes. When near-infrared (NIR) irradiation on the PBFS platform, PB nanocubes trigger heat production by photothermal means, due to the action of Marangoni force, the surface tension on the left and right sides of the droplets and bubbles is not uniform, forming a surface tension gradient, thereby driving the movement of the droplets and bubbles. The control platform has good application potential in the field of microchemical reaction and biomedical engineering and brings new solutions to the field of transparent photothermal materials.
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http://dx.doi.org/10.1002/smll.202405878 | DOI Listing |
Langmuir
March 2025
Institut de Science des Matériaux de Mulhouse (IS2M) CNRS, Université de Haute-Alsace, Université de Strasbourg, 15, Rue JCan Starcky─B.P. 2488, 68057 Mulhouse Cedex, France.
Contact angles of silicone oil droplets and air bubbles settled on a solid substrate and confined in binary ethylene glycol/water mixtures were studied as a function of ethylene glycol concentration. Despite similar reductions in interfacial tensions for both systems, distinct wetting behaviors were observed. While the air bubble contact angle increased with ethylene glycol concentration, the silicone oil droplet exhibited a more complex response, characterized by a stable contact angle at low ethylene glycol concentrations followed by an increase at higher concentrations.
View Article and Find Full Text PDFAnal Chem
March 2025
Department of Chemistry, Western Michigan University, Kalamazoo, Michigan 49008, United States.
Nanobubbles (NBs) are very small gas-filled cavities in solvents, and when their sizes reach diameters around 200 nm, they remain in solution for extended periods of time, featuring special chemical and physical properties. Here, we investigate the application of NBs in electrospray ionization. We show that the addition of CO or N NBs into spray solvents significantly improves signal responses of small molecules in both positive and negative modes during ESI-MS.
View Article and Find Full Text PDFACS Nano
March 2025
School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
Liquid-vapor phase-change heat transfer plays an important role in many industrial systems, ranging from power generation and air conditioning to water desalination, food processing, and thermal management of electronics and data centers. Recent advances in micro/nanofabrication have enabled desirable manipulation of multiscale dynamics governing droplet/bubble motion and capillary liquid flows for highly efficient phase-change heat transfer. However, there lacks a comprehensive review on the design and fabrication of micro/nanostructured surfaces with controlled morphology and wettability, to enhance the diverse phase-change heat transfer processes.
View Article and Find Full Text PDFLangmuir
March 2025
Department of Radiology, University of Michigan, Ann Arbor, Michigan 48109-5667, United States.
Shell-stabilized, phase-shift droplets of perfluorocarbon have shown promising potential in diagnostic and therapeutic ultrasound applications. While the role of shell composition has been well-studied for conventional gas-filled microbubbles, its influence on bubbles generated via acoustic droplet vaporization (ADV) remains understudied. This study investigates the effect of shell composition─lipid, protein, and polymer─on the stability, ADV dynamics, growth behavior, release kinetics, and acoustic response of perfluorohexane phase-shift droplets.
View Article and Find Full Text PDFUltrason Sonochem
March 2025
Cancer Center, Department of Ultrasound Medicine, Zhejiang Provincial People's Hospital, Affiliated People's Hospital of Hangzhou Medical College, Hangzhou, Zhejiang, China. Electronic address:
Histotripsy is a cavitation-based tumor ablation technology. To achieve precise cavitation-based ablation requires investigating the cavitation behavior of the bubble cloud and their impact on tumor tissue. This study explored the cavitation behavior of bubble clouds generated by perfluoropentane (PFP)-loaded nanodroplets and efficacy of bubble cloud cavitation in tumor ablation under varying ultrasound intensities.
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