Unlocking epoxy thermal management capability via hierarchical Ce-MOF@MoS hybrid constructed by in-situ growth method.

J Colloid Interface Sci

State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, PR China. Electronic address:

Published: January 2025

AI Article Synopsis

  • * The resulting composite, EP/Ce-MOF@MoS-3, demonstrates significantly enhanced tensile strength (50.87 MPa) and elongation at break (10.84%), alongside improved flame resistance and lower heat release rates.
  • * Additionally, at a 3% loading, the Ce-MOF@MoS hybrid reduces carbon monoxide (CO) and carbon dioxide (CO2) emissions by 48.8% and 38.7%, respectively, highlighting its potential for safer, more efficient EP nanocomposites

Article Abstract

This study demonstrates the preparation of needle-like Ce-MOF crystals on molybdenum disulfide (MoS) nanosheets using in-situ growth technology. This hybrid structure significantly enhances the thermal management and mechanical properties of thermosetting epoxy resin (EP). Specifically, EP/Ce-MOF@MoS-3 exhibits a notable increase in tensile strength (TS) to 50.87 MPa and elongation at break (EB) to 10.84 %. Moreover, Ce-MOF@MoS provides synergistic flame retardant benefits, reducing the peak heat release rate (pHRR) and total heat release (THR) of EP/Ce-MOF@MoS-3 by 38 % and 12.64 %, respectively, compared to EP-0. Additionally, Ce-MOF@MoS suppresses smoke and reduces toxic emissions; at a 3 % loading, it decreases CO and CO production in EP nanocomposites by 48.8 % and 38.7 %, respectively. Thus, this Ce-MOF@MoS hybrid, synthesized via in-situ growth, offers a novel approach for developing EP nanocomposites with superior thermal management and mechanical properties, along with effective flame retardancy and reduced hazardous emissions during thermal events.

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http://dx.doi.org/10.1016/j.jcis.2024.09.176DOI Listing

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