Stabilizing ultra-close Pt clusters on all-in-one CeO/AlO fibril-in-tubes against sintering.

Metal sintering poses significant challenges for developing reliable catalytic systems toward high-temperature reactions, particularly those based on metal clusters with sizes below 3 nm. In this work, electrospun dual-oxide fibril-in-tubes consisting of CeO and AlO are rationally designed in an all-in-one manner, to stabilize 2.3 nm Pt clusters with a Tammann temperature (sintering onset temperature) lower than 250 °C. The abundant pores and channels effectively stabilize the Pt clusters physically, while the strong support, CeO, with high adhesion, pins Pt clusters firmly, and the adjacent weak support, AlO, with low adhesion, provides energy barriers to prevent the clusters and emitted Pt atom(s) from moving across the support. Therefore, the ultra-close 2.3 nm Pt clusters, featuring an average nearest neighboring distance of only 2.1 nm, were carefully stabilized against sintering at temperatures exceeding 750 °C, even in oxidative and steam-containing environments. In addition, this catalytic system can efficiently and durably serve in diesel combustion, a high-temperature exothermic reaction, showing no activity decline after 5 cycles. This work provides a comprehensive understanding of sinter-resistant catalytic systems, and presents new insights for the development of advanced nanocatalysts.