The use of immobilized microbial technology in wastewater treatment has drawn extensive attention due to its advantages of high colony density, rapid reaction speed, and good stability. Immobilization carriers are the core of immobilization technology. This review summarizes the types of immobilization carriers and their advantages and disadvantages, focusing on the potential for utilizing novel immobilization carriers (composite carriers, nanomaterials, metal-organic frameworks (MOFs), and biochar materials) in wastewater applications. The basic principles and technical advantages and disadvantages of novel immobilization methods (layer-by-layer self-assembly (LBL) and electrostatic spinning) are then summarized. Additionally, the research progress and application characteristics of immobilized anaerobic ammonia oxidizing (Anammox) and aerobic denitrifying (AD) bacteria for enhanced wastewater nitrogen removal are discussed. Finally, the current challenges of immobilized microbial technology are discussed, and its future development trends are summarized and prospected. This review provides guidance and theoretical support for the practical engineering application of immobilized microbial technology.
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