The rare examples of discrete anionic halobismuthates(III) with group 11 elements were obtained. Those are (3-MePyH)[BiCuI] () and (3,5-MePyC)[BiAgI] () (3-MePyH = 3-methylpyridinium cation, 3,5-MePyC=1,6-bis(3,5-dimethylpyridinium)hexane dication). Both complexes were isolated as pure phases; the optical band gaps for and are 1.75 and 2.23 eV, respectively.
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| http://dx.doi.org/10.1021/acs.inorgchem.4c02792 | DOI Listing |
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