Phthalates, categorized as a main constituent of endocrine-disrupting chemicals (EDCs), are present in polymeric products. These substances can enter the environment through several pathways, including improper handling, which leads to their presence in toilet water, floor washings, surface runoff, and landfill leachate. This study focuses on the performance analysis of nanocomposite materials made of polymer (polypyrrole), quasi-metal (graphene oxide), and biochar (from palmyra seed) for the elimination of diethyl phthalates (DEP) from aqueous environments. Scanning electron microscope (SEM), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR) were used to describe the nanocomposite characteristics. The experimental results supported a chemisorption process by agreeing well with the pseudo-second order. The Langmuir isotherm explained the DEP sorption data, which aligned to monolayer DEP adsorption on the nanocomposite surface. With a binding affinity of -13.36 (kcal/mol) and the highest docking score, Diethyl phthalates and graphene oxide interaction is validated. The produced nanocomposite is suggested as a possible alternative for the sorption of DEP. Future applications could benefit from the higher adsorption capacity, and environmental friendliness of nanocomposites.
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http://dx.doi.org/10.1016/j.envres.2024.120032 | DOI Listing |
Pharmaceutics
December 2024
Department of General Surgery, The Fifth People's Hospital of Shanghai, Fudan University, Shanghai 200240, China.
Background/objectives: Colorectal cancer (CRC) is characterized by a high rate of both incidence and mortality, and its treatment outcomes are often affected by recurrence and drug resistance. Ferroptosis, an iron-dependent programmed cell death mechanism triggered by lipid peroxidation, has recently gained attention as a potential therapeutic target. Graphene oxide (GO), known for its oxygen-containing functional groups, biocompatibility, and potential for functionalization, holds promise in cancer treatment.
View Article and Find Full Text PDFPlants (Basel)
December 2024
Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering, Nanjing University of Information Science and Technology, Nanjing 210044, China.
Global pollution caused by micro/nanoplastics (M/NPs) is threatening agro-ecosystems, compromising food security and human health. Also, the increasing use of graphene-family nanomaterials (GFNs) in agricultural products has led to their widespread presence in agricultural systems. However, there is a large gap in the literature on the combined effects of MNPs and GFNs on agricultural plants.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Institute of Optoelectronics, Military University of Technology, gen. S. Kaliskiego 2, 00-908 Warsaw, Poland.
In order to improve the performance of cement mortar (Portland cement), it was enriched with triclosan, hypochlorous acid, silver nanoparticles and graphene oxide. Cement mortar is used, among other things, to fill the gaps between the tiles of building porcelain stoneware. A number of structural, mechanical and biological tests were carried out.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Cracow University of Technology, Faculty of Chemical Engineering and Technology, Warszawska 24, 31-155 Krakow, Poland.
Direct lithium extraction from unconventional resources requires the development of effective adsorbents. Crown ether-containing materials have been reported as promising structures in terms of lithium selectivity, but data on adsorption in real, highly saline brines are scarce. Crown ether-grafted graphene oxides were synthesized using 2-hydroxymethyl-12-crown-4, hydroxy-dibenzo-14-crown-4 and epichlorohydrin as a source of anchoring groups.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Department of Chemical Engineering, Faculty of Chemistry, Campus of Espinardo, University of Murcia, 30100 Murcia, Spain.
Nowadays, there is a growing interest in membrane modification processes to improve their characteristics and the effectiveness of their treatments and reduce the possible fouling. In this sense, in this work, a modification of an ultrafiltration membrane with three different materials has been carried out: reduced graphene oxide (rGO), chitosan and MgCl. For both the native and the modified membranes, a study has been carried out to remove the emerging contaminant sulfamethoxazole (SMX).
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