Complex 1 [(C^C)Au(dppv)]PF (dppv = -1,2-diphenylphosphinoethylene) is reported to react efficiently and selectively with aliphatic and aromatic thiols in the presence of a base. This methodology enables the smooth introduction of various functional groups on the [(C^C)Au(P^P)] scaffold.
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Post-metallation functionalization of the [(C^C)Au(P^P)] scaffold through a hydrothiolation reaction.
Dalton Trans
October 2024
Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, IPCM, F-75005 Paris, France.
Complex 1 [(C^C)Au(dppv)]PF (dppv = -1,2-diphenylphosphinoethylene) is reported to react efficiently and selectively with aliphatic and aromatic thiols in the presence of a base. This methodology enables the smooth introduction of various functional groups on the [(C^C)Au(P^P)] scaffold.
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