Extended system-bath entanglement theorem with multiple baths in the presence of external fields.

J Chem Phys

Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui 230026, China.

Published: September 2024

AI Article Synopsis

  • The system-bath entanglement theorem (SBET) connects the properties of an entangled system and its environment to individual system and bath attributes, initially established through linear response and correlation functions.
  • The current work expands the SBET to include field-dressed scenarios with several baths at varying temperatures, acknowledging that external fields interact not just with the system but also with its environment.
  • This extension of SBET can enhance research in areas like photo-acoustic, photo-thermal, and pump-probe studies, while also addressing field-free conditions and classical equivalents of the theorem.

Article Abstract

The system-bath entanglement theorem (SBET) was established in terms of linear response functions [Du et al., J. Chem. Phys. 152, 034102 (2020)] and generalized to correlation functions [Su et al., J. Chem. Phys. 160, 084104 (2024)] in our previous studies. This theorem connects the entangled system-bath properties to the local system and bare-bath ones. In this work, we extend the SBET to field-dressed conditions with multiple baths at different temperatures. As in reality, the external fields may interact with not only the system but also environments. The extended SBET facilitates, for example, photo-acoustic, photo-thermal, pump-probe related studies. The theorem under the field-free condition (multiple baths) and its counterpart in the classical limit is also presented.

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http://dx.doi.org/10.1063/5.0226351DOI Listing

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