Progress and perspectives on the reaction mechanisms in mild-acidic aqueous zinc-manganese oxide batteries.

The appeal of safe, energy-dense, and environmentally-friendly MnO as a cathode for rechargeable aqueous zinc-metal oxide batteries (AZMOBs) has attracted significant research attention, but unexpected complexities have resulted in a decade of confusion and conflicting claims. The literature base is near saturation with a mix of efforts to achieve practical, rechargeable Zn-ion batteries and to untangle the presented electrochemical mechanisms. We have summarized the respective mechanisms and contextualized the respective justifications. As new perspectives arise from and techniques, renewed efforts must solidify mechanistic understandings and reconcile disparate data through judicial application of modelling. In light of a variety of MnO cathode phases and stable, -stable, and complex reaction products, this perspective emphasizes the need for greater supplementation of the and characterization with modelling, such as density functional theory. Through the elucidation of key mechanisms under dynamic operating and characterization conditions, the body of previously contradictory research and routes to practical batteries may be unified, and guide the way to longevity and grid-scale applicable charge rates and capacity.