Revealing the impact of wildfires on groundwater quality: Insights from Sierra de la Culebra (Spain).

Wildfires induce changes in soil and vegetation composition, significantly impacting the hydrological cycle and altering future runoff and infiltration patterns. Ash residue on the ground can infiltrate the subsoil along with water, leading to modifications in groundwater hydrochemistry. Climate change and summer heatwaves can create favourable conditions for severe wildfires, such as the one that occurred in Zamora, Spain, in 2022. Fourteen simultaneous points of origin across various locations in Zamora triggered the worst environmental disaster in this province, as well as the largest fire recorded in the history of Spain. Following the severe wildfires in Sierra de la Culebra, Zamora, groundwater samples were obtained to compare the hydrochemistry with pre-fire background data spanning several years. A general decline in pH across all sampling points was observed, most notably at Z1, likely due to its very high permeability and leaching of organic acids from burned vegetation. Increases in major ions such as SO and NO were detected at Z1-2, while HCO levels decreased, indicating possible oxidation of soil organic matter and the introduction of wildfire-derived organic acids into the groundwater system. Elevated concentrations of Na, K, Mg, and Ca were observed at Z3, suggesting possible ash residue infiltration. Despite the severity of the wildfires, the results indicate that there were no significant long-lasting impacts on groundwater quality overall. This finding suggests that the groundwater systems in the study area are resilient to such environmental catastrophes.