Statement Of Problem: The clinical success of ceramic veneers cemented with preheated composite resin has been reported to be acceptable. Although the cementing technique requires sufficient light energy to activate its polymerization, the ability of light to penetrate through ceramic restorations of different thicknesses is unclear.
Purpose: The purpose of this in vitro study was to evaluate the polymerization quality and bond joint thickness of a dual-component adhesive and a heated composite resin when bonding ceramic onlays of varying thicknesses.
Material And Methods: Sixty noncarious maxillary premolars, extracted for orthodontic or periodontal reasons, were divided into 6 groups (n=10) and sectioned apically to the marginal ridge. Computer-aided design and computer-aided manufacturing (CAD-CAM) was used to create onlays of varying thicknesses. Following the manufacturers ' instructions, the onlays were cemented using a dual-polymerizing resin for group DP1, DP2, and DP3 groups and preheated light-polymerizing resin for groups LP1, LP2, and LP3. The numbers indicate onlay thickness in each group. Vickers testing was performed 24 hours after polymerization, with a 0.49-N static load applied for 10 seconds. Film thickness was analyzed under an optical microscope, and temperature changes were measured using a thermal imaging camera. Statistical analysis was done with the 2-factor mixed ANOVA tests (α=.05).
Results: The Vickers hardness of a dual-polymerizing cement was lower compared with heated light-polymerizing cement (P<.05). Moreover, the thickness of the resin-ceramic restoration did not significantly affect the polymerization of a dual-polymerizing cement. However, the polymerization of the preheated light-polymerizing composite resin in group LP3 was significantly lower compared with other thicknesses (P<.05). In group LP3, the Vickers hardness of the tooth adjacent to the surface of the cement (DX2) was lower compared with indentations closer to the restoration surface (DX3, DX6), demonstrating a reduction in polymerization in the internal part. In addition, the mean film thickness of the dual-polymerizing groups (96 ±18 µm) was significantly lower than of the heated light-polymerizing groups (294 ±64 µm) (P<.05). A temperature reduction of 15 °C in the heated composite resin was also observed after 8 seconds CONCLUSIONS: The thickness of the ceramic restoration did not significantly affect the polymerization of a dual-polymerizing cement. However, the polymerization of the preheated light-polymerizing composite resin under the same ceramic restoration with a thickness of 3 mm was significantly lower. In addition, the mean film thickness for the dual-polymerizing composite resin groups was significantly lower than for the heated light-polymerizing composite resin groups.
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http://dx.doi.org/10.1016/j.prosdent.2024.09.004 | DOI Listing |
Nat Commun
January 2025
National Key Laboratory of Advanced Micro and Nano Manufacture Technology, School of Materials Science and Engineering, Peking University, Beijing, China.
On-site or in-sensor biosignal transduction and amplification can offer several benefits such as improved signal quality, reduced redundant data transmission, and enhanced system integration. Ambipolar organic electrochemical transistors (OECTs) are promising for this purpose due to their high transconductance, low operating voltage, biocompatibility, and suitability for miniaturized amplifier design. However, limitations in material performance and stability have hindered their application in biosignal amplification.
View Article and Find Full Text PDFJ Environ Manage
January 2025
GAIKER Technology Centre, Basque Research and Technology Alliance (BRTA), Parque Tecnológico, Edificio 202, 48170, Zamudio, Spain.
Current industrial separation and sorting technologies struggle to efficiently identify and classify a large part of Waste of Electric and Electronic Equipment (WEEE) plastics due to their high content of certain additives. In this study, Raman spectroscopy in combination with machine learning methods was assessed to develop classification models that could improve the identification and separation of Polystyrene (PS), Acrylonitrile Butadiene Styrene (ABS), Polycarbonate (PC) and the blend PC/ABS contained in WEEE streams, including black plastics, to increase their recycling rate, and to enhance plastics circularity. Raman spectral analysis was carried out with two lasers of different excitation wavelengths (785 nm and 1064 nm) and varying setting parameters (laser power, integration time, focus distance) with the aim at reducing the fluorescence.
View Article and Find Full Text PDFTalanta
December 2024
Key Laboratory for Analytical Science of Food Safety and Biology, College of Chemistry, Fuzhou University, Fuzhou, 350116, China; International (HongKong Macao and Taiwan) Joint Laboratory on food safety and environmental analysis, Fuzhou, 350116, Fuzhou University, China; Engineering Technology Research Center on Reagent and Instrument for Rapid Detection of Product Quality and Food Safety, Fuzhou, 350116, China. Electronic address:
The release of microcystin (MCs) in aquatic ecosystems poses a substantial risk to the safety of irrigation and drinking water. In view of the challenges associated with monitoring MCs in water bodies, given their low concentration levels (μg/L to ng/L) and the presence of diverse matrix interferences, there is an urgent need to develop an efficient, cost-effective and selective enrichment technique for MCs prior to its quantification. In this work, a gold nanoparticles (AuNPs)-functionalized zwitterionic polymer monolith was described and further applied for the affinity enrichment of MCs.
View Article and Find Full Text PDFJ Food Drug Anal
December 2024
Department of Medical Laboratory Science and Biotechnology, Kaohsiung Medical University, Kaohsiung, Taiwan.
This study introduces an innovative bio-based sorbent bead crafted by integrating chitosan (CS) biopolymers, Fe(NO3)3 and polydopamine nanoparticles (PDA NPs) via glutaraldehyde crosslinking. The primary focus of this study was the concurrent separation of diverse tetracycline antibiotics (TCs), followed by rigorous reversed-phase liquid chromatography analysis. The fabricated CS/Fe@PDA sorbent beads were comprehensively characterized using scanning electron microscopy and energy-dispersive X-ray spectroscopy, revealing a surface rich in active carbon (C), nitrogen (N), and oxygen (O) moieties.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Laser Thermal Laboratory, Department of Mechanical Engineering, University of California, Berkeley, California 94720, United States.
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