Engineering high-brightness and long-lived organic room-temperature phosphorescence systematic molecular design.

Phys Chem Chem Phys

State Key Laboratory of Organometallic Chemistry and Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Ningbo Zhongke Creation Center of New Materials, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, People's Republic of China.

Published: October 2024

AI Article Synopsis

  • Researchers developed BF2bdk-based afterglow emitters with impressive photoluminescence quantum yields of up to 46.3%.
  • These emitters have long lifetimes of about 1 second, which makes them suitable for various applications.
  • Key factors influencing their afterglow properties include the types of excited states, the variety of excited state forms, small energy gaps between singlet and triplet states, and strong dipole interactions.

Article Abstract

We report a systematic molecular design in BF2bdk-based afterglow emitters with photoluminescence quantum yields up to 46.3% and lifetimes around 1 s. Suitable excited-state types, diverse excited state species, relatively small singlet-triplet energy gaps and strong dipole-dipole interactions are critical in determining the afterglow properties.

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Source
http://dx.doi.org/10.1039/d4cp02927eDOI Listing

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