In this work, a flexible polyurethane (PU) foam/polymer/clay (PUF/PAASep) composite is prepared via a simple dip-coating method. The composite exhibits excellent damping properties under quasi-static compression, vibration transmissibility, and impact resistance. For the composite preparation, sepiolite (Sep) dispersion in a polyacrylic acid (PAA) solution is first homogenized and evaluated using microscopy, and the obtained PAASep suspension is used to coat the PU foam uniformly for optimization of the quasi-static mechanical performance of the foam composites. The PU foam struts coated with 1 wt % PAA and 3 wt % sepiolite are strengthened, resulting in an 8-fold improvement of the stiffness and three-times increase of the impact force resistance compared to the uncoated PU foams. More importantly, the PU foam composites show a remarkable vibration damping capability, with the loss modulus 57 times that of the uncoated PU foams, enabled by micro friction and stick-slip effects mediated by the PAASep coatings. The facile prepared PAASep-coated PU foams have significant potential for cushioning, packaging, and broad engineering applications involving energy absorption.
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http://dx.doi.org/10.1021/acsapm.4c01437 | DOI Listing |
3D Print Addit Manuf
October 2024
School of Materials Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu, China.
Currently, there is great demand for flexible three-dimensional (3D) printable thermoplastic polyurethane (TPU) wires with excellent ultraviolet (UV) resistance, which have broad application prospects in wearable products. In this study, UV-resistant TPU composites were obtained using a blending modification method. The relationship between the optimized parameters of fused deposition modeling 3D printing and mechanical properties of the TPU composite is discussed using an orthogonal test.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Institute of Functional Materials, Research Base of Textile Materials for Flexible Electronics and Biomedical Applications (China Textile Engineering Society), Shanghai Key Laboratory of Lightweight Composite, Shanghai Engineering Research Center of Nano Biomaterials and Regenerative Medicine, Donghua University, Shanghai, 201620, P. R. China.
Flammability is a significant challenge in polymer-based electronics. In this regard, triboelectric nanogenerators (TENGs) have enabled a safe means for harvesting mechanical energy for conversion into electrical energy. However, most existing polymers used for TENGs are sourced from petroleum-based raw materials and are highly flammable, which can further accelerate the spread of fire and harm the ecological environment.
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December 2024
Department of Dentistry, National Yang Ming Chiao Tung University, Taipei, Taiwan.
The purpose of this study was to investigate the effects of acetyl tributyl citrate (ATBC) on the mechanical properties, abrasion resistance, and cytotoxicity of a polyurethane-based 3D printing resin for mouthguard applications. The synthesized polycarbonate-based polyurethane acrylate was formulated into digital light processing printing resins with 40 wt% triethylene glycol dimethacrylate, and different percentage of ATBC were added for further characterizations. The mechanical properties and abrasion resistance, ATBC migration, and the cytotoxicity of the resins were evaluated.
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December 2024
Institute of Materials Science and Engineering, Faculty of Mechanical Engineering, Lodz University of Technology, Łódź, Poland.
ACS Appl Mater Interfaces
December 2024
College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China.
Polyurethane sponge is frequently selected as a substrate material for constructing flexible compressible sensors due to its excellent resilience and compressibility. However, being highly hydrophilic and flammable, it not only narrows the range of use of the sensor but also poses a great potential threat to human safety. In this paper, a conductive flexible piezoresistive sensor (CHAP-PU) with superhydrophobicity and high flame retardancy was prepared by a simple dip-coating method using A-CNTs/HGM/ADP coatings deposited on the surface of a sponge skeleton and modified with polydimethylsiloxane.
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