The critical period of crop-weed competition (CPCWC) varies by cultivars, management strategies, cropping seasons, soil, and climate. Hence, a study was done to assess CPCWC in green gram under different cropping seasons and its impact on nutrient mining, agro-physiological characteristics, and productivity of green gram during the summer and rainy seasons. The experiment comprised of 12 treatments (weed interference until 10, 20, 30, 40, 50 days after sowing (DAS) and crop maturity, weed-free until 10, 20, 30, 40, 50 DAS and crop maturity). The treatments were placed in a randomized complete block design (RCBD) with three replications. Results revealed that, summer green gram outperformed rainy green gram by boosting nutrient uptake, growth and productivity. Weed interference up to crop harvest lowered the green gram dry matter accumulation by 34.11 %, seed index by 8.98 %, grain yield by 76.21 % and biological yield by 31.06 %. However, weed-free until crop harvest boosted nitrogen content by 50.4 %, phosphorus by 87.7 % and potassium by 42.9 %. Similarly, weed-free environment until harvest of the crop raised chlorophyll-a content by 2.9-6.6 fold and 2.7-7.0 fold, chlorophyll-b by 3.8-5.8 fold and 3.8-6.5 fold over season-long weedy plots during summer and rainy season, respectively. This study suggested that the critical duration for crop-weed competition under 5 % relative yield loss (RYL) was 11-43 DAS in summer and 4 to 36 DAS in rainy. Whereas, critical duration for the crop-weed competition at 10 % RYL was 21-36 DAS in summer and 8 to 27 DAS in rainy seasons.
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http://dx.doi.org/10.1016/j.heliyon.2024.e36855 | DOI Listing |
Nat Commun
January 2025
Research Center for Solar Driven Carbon Neutrality, School of Physics Science and Technology, In-stitute of Life Science and Green Development, Hebei University, Baoding, 071002, PR China.
Photo-oxidation of methane (CH) using hydrogen peroxide (HO) synthesized in situ from air and water under sunlight offers an attractive route for producing green methanol while storing intermittent solar energy. However, in commonly used aqueous-phase systems, photocatalysis efficiency is severely limited due to the ultralow availability of CH gas and HO intermediate at the flooded interface. Here, we report an atomically modified metal-organic framework (MOF) membrane nanoreactor that promotes direct CH photo-oxidation to methanol at the gas-solid interface in a reticular open framework.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
State Key Laboratory of Bioreactor Engineering, East China University of Science and Technology, Shanghai 200237, China.
Taming highly enolizable aldehydes for catalytic asymmetric C-C coupling with nucleophiles remains an elusive challenge compared to widely explored simple alkyl or aryl aldehydes. Herein, we use ThDP-dependent enzymes to realize the direct C-C coupling of highly enolizable 2-phosphonate aldehydes with in situ-generated dynamically reversible nucleophiles (acyl anions). Unlike NHC-mediated reactions that yield complex mixtures of multiple adducts, our enzymatic process selectively produces biologically active β-hydroxy phosphonates with high yields (up to 95%) and excellent enantioselectivities (up to 99% ee).
View Article and Find Full Text PDFOrg Biomol Chem
January 2025
Nanotec-CU Center of Excellence on Food and Agriculture, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand.
The bromination of α-oxo ketene dithioacetals using KBr/HO, catalyzed by vanadium chloroperoxidase (VCPO), has been successfully demonstrated. A comparative study of enzymatic processes "on water" "in water", using 2 wt% of the surfactant TPGS-750-M revealed that the in-water protocol not only provides higher yields but also accommodates a broader substrate scope. This bromination method in an aqueous micellar medium enabled the preparation of brominated α-oxo ketene dithioacetals in fair to excellent yields (23 examples).
View Article and Find Full Text PDFBiotechnol Notes
December 2024
Department of Chemistry, Faculty of Science, Agriculture, and Engineering, University of Zululand, Private Bag X1001, KwaDlangezwa, 3886, South Africa.
Nanotechnology is a rapidly expanding field with diverse healthcare, agriculture, and industry applications. Central to this discipline is manipulating materials at the nanoscale, particularly nanoparticles (NPs) ranging from 1 to 100 nm. These NPs can be synthesized through various methods, including chemical, physical, and biological processes.
View Article and Find Full Text PDFNat Commun
January 2025
School of Nuclear Science and Technology, Key Laboratory of Precision and Intelligent Chemistry, National Synchrotron Radiation Laboratory, School of Chemistry and Materials Science, Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, PR China.
Solar-driven, selective biomass hydrogenation is recognized as a promising route to renewable chemicals production, but remains challenging. Here, we report a TiO supported Cu single-atom catalyst with a four-coordinated Cu-O structure, which can be universally applied for solar-driven production of various renewable chemicals from lignocellulosic biomass-derived platform molecules with good yields using green methanol as a hydrogen donor, to address this challenge. It is significant that the biomass upgrading driven by natural sunlight on a gram scale demonstrates the great practical potential.
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