Arsenic and fluoride occurrence in groundwater of an alluvial fan-delta junction zone in an arid climate: Implication for potential health risk and irrigation water quality.

Alluvial fans and deltas are two environments with different hydrochemical conditions. Their junction zones, as mixing environments, are variably influenced by different processes, leading to variable environmental conditions. The purpose of this study is to investigate groundwater quality in the junction zone of these environments in the northern part of the Jazmourian depression (known as the Rudbar plain) in southeastern Iran to determine the dominant processes, assess arsenic and fluoride health risks, and evaluate irrigation water quality. A total of 33 samples from deep drilled wells were taken, and the concentrations of major ions and elements were determined. Additionally, statistical and hydrochemical analyses were undertaken. The dominant processes in the delta are evaporation and ion exchange, while the dominant process in the fan environment is silicate hydrolysis. Among the samples, 26.7% were mainly affected by the delta, and 73.3% were mainly affected by fan conditions. Although the majority of groundwater samples were suitable for irrigation based on quality standards, a significant portion exceeded the acceptable level for Na%. Non-carcinogenic health risk assessments indicated that arsenic hazard risks exceeded thresholds in 63.3% of cases for children and 36% for adults. Carcinogenic health risks associated with arsenic and fluoride exceeded acceptable levels in 4 and 2 stations, respectively. Elevated As concentrations contribute to a greater average health risk in parts of fans environment.