It is crucial to explore the intrinsic mechanisms that influence thermometric sensitivity. This study investigates the optical performance of materials with the same crystal structure but different phonon energies. LnOS:Er/Yb (Ln = La/Gd/Y) phosphors with similar morphology and particle sizes were prepared to systematically study the influence of different phonon energy matrices on optical properties. The intrinsic mechanism was elucidated through the matching degree between the energy gap and phonon energy, Judd-Ofelt (J-O) theory, and quantum dielectric theory. It was ultimately concluded that the combination of high phonon energy with a large Ω and a small Ω is beneficial for enhancing the sensitivity of temperature sensing materials.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1364/OL.534951 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Metallic Bonding in Close-Packed Structures: Structural Frustration from a Hidden Gauge Symmetry.
Phys Rev Lett
December 2024
Department of Physics, Brock University, St. Catharines, Ontario L2S 3A1, Canada.
Based on its simple valence electron configuration, we may expect lithium to have straightforward physical properties that are easily explained. However, solid lithium, when cooled below 77 K, develops a complex structure that has been debated for decades. A close parallel is found in sodium below 36 K where the crystal structure still remains unresolved.
View Article and Find Full Text PDFAchieving Superior Thermoelectric Performance in Methoxy-Functionalized MXenes: The Role of Organic Functionalization.
ACS Appl Mater Interfaces
January 2025
College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, P. R. China.
Thermoelectric technology enables the direct and reversible conversion of heat into electrical energy without air pollution. Herein, the stability, electronic structure, and thermoelectric properties of methoxy-functionalized MC(OMe) (M = Sc, Ti, V, Cr, Y, Zr, Nb, Mo, Hf, Ta, and W) were systematically investigated using first-principles calculations and semiclassical Boltzmann transport theory. All MXenes, except those with M = Cr, Mo, and W, can be synthesized by substituting Cl- and Br-functionalized MXenes with deprotonated methanol, with stability governed by the M-O bond strength.
View Article and Find Full Text PDFResisting High-Energy Impact Events through Gap Engineering in Superconducting Qubit Arrays.
Phys Rev Lett
December 2024
Google Quantum AI, Santa Barbara, California 93117, USA.
Quantum error correction (QEC) provides a practical path to fault-tolerant quantum computing through scaling to large qubit numbers, assuming that physical errors are sufficiently uncorrelated in time and space. In superconducting qubit arrays, high-energy impact events can produce correlated errors, violating this key assumption. Following such an event, phonons with energy above the superconducting gap propagate throughout the device substrate, which in turn generate a temporary surge in quasiparticle (QP) density throughout the array.
View Article and Find Full Text PDFSuperdiffusive Thermal Transport in Polymer-Grafted Nanoparticle Melts.
Phys Rev Lett
December 2024
Center for Phononics and Thermal Energy Science, School of Physics Science and Engineering, Tongji University, Shanghai 20092, China.
In contrast to normal diffusion processes, thermal conduction in one-dimensional systems is anomalous. The thermal conductivity is found to vary with the length as κ∼L^{α}(α>0), but there is a long-standing debate on the value α. Here, we present a canonical example of this behavior in polymer-grafted spherical nanoparticle (GNP) melts at fixed grafting density and nanoparticle radius.
View Article and Find Full Text PDFRational design of stable carbon nitride monolayer membranes for highly controllable CO capture and separation from CH and CH.
Nanoscale
January 2025
Advanced Materials Science Innovation Center, Longmen Laboratory, Luoyang 471003, China.
CO capture and separation from natural and fuel gas are important industrial issues that refer to the control of CO emissions and the purification of target gases. Here, a novel non-planar g-CN monolayer that could be synthesized the supramolecular self-assembly strategy was identified using DFT calculations. The cohesive energy, phonon spectrum, BOMD, and mechanical stability criteria confirm the stability of the g-CN monolayer.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!