In recent years, the power conversion efficiency of perovskite solar cells has increased rapidly. Perovskites can be prepared using simple and cost-effective solution methods. However, the perovskite films obtained are usually polycrystalline and contain numerous defects. Passivation of these defects is crucial for enhancing the performance of solar cells. Here, we report the use of propylamine hydroiodide (PAI) for defect passivation. We found that PAI can result in higher-efficiency cells by reducing the defects and suppressing non-radiative recombination. Consequently, n-i-p perovskite solar cells with a certificated efficiency of 21% were obtained. In addition, PAI exhibited excellent performance in p-i-n devices by serving as a buried interface layer, leading to an improved efficiency of 23%.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11397452 | PMC |
http://dx.doi.org/10.3390/nano14171416 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Institute of Advanced Materials (INAM), Universitat Jaume I, Av. Vicent Sos Baynat, s/n, 12071 Castellón de la Plana, Spain.
High defect concentrations at the interfaces are the basis of charge extraction losses and instability in perovskite solar cells. Surface engineering with organic cations is a common practice to solve this issue. However, the full implications of the counteranions of these cations for device functioning are often neglected.
View Article and Find Full Text PDFACS Nano
January 2025
State Key Laboratory of Wide-Bandgap Semiconductor Devices and Integrated Technology, Faculty of Integrated Circuit, Xidian University, 710071 Xi'an, China.
Flexible perovskite solar cells (FPSCs) have advanced significantly because of their excellent power-per-weight performance and affordable manufacturing costs. The unsatisfactory efficiency and mechanical stability of FPSCs are bottleneck challenges that limit their application. Here, we explore the use of octylammonium acetate (OAAc) with a long, intrinsic, flexible molecular chain on perovskite films for surface adhesion and mechanical releasing.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Physics, Riphah International University, Islamabad 44000, Pakistan.
Halide perovskites are a class of materials with excellent potential for solar cell applications due to their excellent optical and electronic properties. In this study, strain-dependent physical properties of SrNBr perovskites are investigated and theoretical results are reported here. The structural properties indicate that SrNBr has a cubic structure.
View Article and Find Full Text PDFAdv Mater
January 2025
Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Metal halide perovskite solar cells (PSCs) have emerged as one of the most promising candidates for next-generation photovoltaic technologies. However, perovskite films deposited by blade-coating usually exhibit inferior film morphology compared to those fabricated by spin-coating, which hinders the power conversion efficiency (PCE) and stability of the scalable perovskite solar modules (PSMs). Herein, ellipsoidal colloids are tailored in the perovskite precursor solution by incorporating perovskite colloids and polymer additives.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Peking University, College of Chemistry and Molecular Engineering, Chengfu Road No.292, 100871, Beijing, CHINA.
Organic-inorganic hybrid perovskites have demonstrated great potential for flexible optoelectronic devices due to their superior optoelectronic properties and structural flexibility. However, mechanical deformation-induced cracks at the buried interface and delamination from the substrate severely constrain the optoelectronic performance and device lifespan. Here, we design a two-site bonding strategy aiming to reinforce the mechanical stability of the SnO2/perovskite interface and perovskite layer using a multifunctional organic salt, 4-(trifluoromethoxy)phenylhydrazine hydrochloride (TPH).
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!