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Article Abstract
The ligands tris(8-quinolyl)stibine and tris(6-methyl-8-quinolyl)stibine have been synthesized and complexed to rhodium using (MeCN)RhCl. The resulting complexes feature an unusual [RhSb] core as a result of the formal insertion of the antimony center into one of the Rh-Cl bonds. Computational analysis using density functional theory (DFT) methods reveals that the resulting Rh-Sb σ bond is polarized toward the Rh atom, suggesting a description of this linkage as a Rh → Sb Z-type interaction.
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Source |
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11389720 | PMC |
| http://dx.doi.org/10.1021/acs.organomet.4c00258 | DOI Listing |
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