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Streamlining Si-O bond formation through cobalt-catalyzed dehydrocoupling. | LitMetric

Herein we report a strategy for the synthesis of organosilicons, including siloxanes, silyl ethers, and aminosilanes, Co-catalyzed dehydrogenative coupling between hydrosilanes and nucleophiles. This discovery represents an expansion of the synthetic toolkit for organosilicon synthesis, forging Si-O and Si-N bonds in the presence of cobalt complexes with salen-type ligands.

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http://dx.doi.org/10.1039/d4cc04144eDOI Listing

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