The reaction of nickel(II) chloride with 3-meth-oxy-aniline yielded di-chlorido-tetra-kis-(3-meth-oxy-aniline)nickel(II), [NiCl(CHNO)], as yellow crystals. The Ni ion is pseudo-octa-hedral with the chloride ions to each other. The four 3-meth-oxy-aniline ligands differ primarily due to different conformations about the Ni-N bond, which also affect the hydrogen bonding. Inter-molecular N-H⋯ Cl hydrogen bonds and short Cl⋯Cl contacts between mol-ecules link them into chains parallel to the axis.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11375595 | PMC |
| http://dx.doi.org/10.1107/S2414314624007764 | DOI Listing |
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