A special nano-filter made of cellulose acetate (CA) was developed, including a 3D hierarchically porous structure. The nano-filter utilized nano-clay (hydrophilic bentonite (NC)), comprising 0.5-1.5 % of its weight. The objective of this study was to evaluate the adsorption properties of four carcinogenic polyaromatic hydrocarbons (benz[α] anthracene (BαA), chrysene (CHR), benzo[β]fluoranthene (BβF), and benzo[α] pyrene (BαP)) during the rice smoking process. The evaluation of the nano-filter encompassed an analysis of its mechanical attributes, surface qualities, morphology, and adsorption efficacy. The experimental results demonstrated that adding NC to the nano-filter composition of CA led to substantial improvements in tensile strength, elongation at break, and maximum load stress values compared to the control group. The nano-filter displayed a uniform and homogeneously distributed arrangement of nanoparticles. The GC-MS analysis demonstrated that the enhanced nano-filter, comprising nano-clay particles, successfully absorbed the polycyclic aromatic hydrocarbons (PAHs) over a 21-day rice smoking period. The performance, removal efficiency and porosity during repetitive filtering and cleaning cycles in the rice samples at different smoking times were approved reusability of CA-NC filter. It is recommended to explore the application of hybrid CA nano-filter s, namely those containing NC, as a cutting-edge filtration technique for smoked food products.
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http://dx.doi.org/10.1016/j.ijbiomac.2024.135391 | DOI Listing |
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January 2025
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, 215123, China.
Bio-inspired by tactile function of human skin, piezoionic skin sensors recognize strain and stress through converting mechanical stimulus into electrical signals based on ion transfer. However, ion transfer inside sensors is significantly restricted by the lack of hierarchical structure of electrode materials, and then impedes practical application. Here, a durable nanocomposite electrode is developed based on carbon nanotubes and graphene, and integrated into piezoionic sensors for smart wearable applications, such as facial expression and exercise posture recognitions.
View Article and Find Full Text PDFMikrochim Acta
January 2025
School of Material Science and Engineering, Henan University of Technology Zhengzhou, Henan, 450001, China.
A simple, fast, and cost-effective colorimetric nitrite (NO) sensor based on ZIF-67-derived CoO nanocomposite (ZCo-2 NC) structure has been developed. The prepared colorimetric sensor (ZCo-2 NC) was employed to sensitively detect NO in drinking water system by the exhibition of promising peroxidase-mimicking nanozyme-like features. The sensor manifest well-determined sensing response with excellent linear and wide range of NO sensitivity (0.
View Article and Find Full Text PDFJ Biomater Appl
January 2025
Biomedical Engineering Graduate Program, Toronto Metropolitan University, Toronto, ON, Canada.
This study explores mesoporous bioactive glasses (MBGs) that show promise as advanced therapeutic delivery platforms owing to their tailorable porous properties enabling enhanced drug loading capacity and biomimetic chemistry for localized, sustained release. This work systematically investigates the complex relationship between MBG composition and surfactant templating on structural evolution, bioactive response, resultant drug loading efficiency and release. A total of 12 samples of sol-gel-derived MBG were synthesized using cationic and non-ionic structure-directing agents (cetyltrimethylammonium bromide, Pluronic F127 and P123) while modulating the SiO/CaO content, generating MBG with surface areas of 60-695 m/g.
View Article and Find Full Text PDFMolecules
December 2024
Shanxi Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China.
Lithium-sulfur (Li-S) batteries have emerged as a promising candidate for next-generation high-energy rechargeable lithium batteries, but their practical application is impeded by the sluggish redox kinetics and low sulfur loading. Here, we report the in situ growth of δ-MnO nanosheets onto hierarchical porous carbon microspheres (HPCs) to form an HPCs/S@MnO composite for advanced lithium-sulfur batteries. The delicately designed hybrid architecture can effectively confine LiPSs and obtain high sulfur loading up to 10 mg cm, in which the inner carbon microspheres with a large pore volume and large specific surface area can encapsulate high sulfur content, and the outer MnO nanosheets, as a catalytic layer, can improve the conversion reaction of LiPSs and suppress the shuttle effect.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Univ. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 - UCCS - Unité de Catalyse et Chimie du Solide, Lille F-59000, France.
Metal-organic frameworks (MOFs) combined with polymers as hybrid materials offer numerous advantages such as enhanced performances through synergistic effects at their interface. The primary challenge in developing polymer/MOF hybrid matrix films is ensuring optimal dispersion and strong adhesion of crystalline MOFs to the polymer without aggregation, weak interaction, or phase separation. In this study, hierarchically porous UiO-66_NH/chitosan (ZrCSx-) films were designed by crystallizing UiO-66_NH within a chitosan (CS) skeleton.
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