A 2D cyanido-bridged architecture Zn-[W(CN)] is smoothly pillared by ,'-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (4DPNDI) into 3D hybrid porous coordination polymer (PCP) {ZnII3(DMA)[W(CN)](4DPNDI)·8DMA}. It shows significant uptake of HO, MeOH or CHCl vapours with easy regeneration to the native form, and breathing-type CO adsorption contrasting non-porosity towards N, providing a new example of a highly flexible porous material.
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| http://dx.doi.org/10.1039/d4cc03141e | DOI Listing |
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