Macromolecular sensing motors from conducting polymers: Polyaniline/methylcellulose composites as stable current sensing supercapacitors.

Int J Biol Macromol

Advanced Materials Research Center, Department of Chemistry, University of Calicut, Thenjipalam 673635, India. Electronic address:

Published: November 2024

Sensing motors and supercapacitors are pivotal in empowering smart systems, honing energy management, and facilitating the seamless integration of responsive electronics. Harnessing the electrochemistry of methylcellulose-polyaniline (MC/PANI) composites, this research delves into their potential applications as reactive current sensing supercapacitors with single connectivity. The electrochemical traits of pristine polyaniline (PANI) and MC/PANI composites were analyzed and assessed for their potential applications in sensors and energy storage devices. With a specific capacitance of 300Fg, the MC/PANI_B3 composite-based device retained 87.01 % capacitance after 2000 cycles. Besides, based on electrical energy as the sensing parameter, the composite exhibited augmented cathodic and anodic current sensitivity of 8.77 mJmA and -8.86 mJmA, respectively. The ameliorated supercapacitor and current sensing parameters of MC/PANI_B3 are ascribed to the percolation threshold content of the conducting phase, which is endowed with optimal hydrogen bond-mediated interactions with methylcellulose (MC), thus confers an expanded chain conformation.

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Source
http://dx.doi.org/10.1016/j.ijbiomac.2024.135312DOI Listing

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