Preparation of Metal-Supported Nanostructured Zeolite Catalysts and their Applications in the Upgrading of Biomass-Derived Furans: Advances and Prospects.

The development of platform chemicals derived from biomass, in particular, 5-hydroxymethylfurfural (5-HMF) and furfural (FUR), is of crucial importance in biorefinery. Over the past decades, metal-supported nanostructured zeolites, in particular, metal-supported hierarchically porous zeolites or metal-encapsulated zeolites, have been extensively elaborated because of their multiple functionalities and superior properties, for example, shape-selectivity, (hydro)thermal stability, tunable acidity and basicity, redox properties, improved diffusion, and intimacy of multiple active sites. In this review, the effects of such properties of metal-supported nanostructured zeolites on the enhanced catalytic performances in furanic compound upgrading are discussed. In addition, the recent rational design of metal-supported nanostructured zeolites is exemplified. Consequently, the ongoing challenges for further developing metal-supported nanostructured zeolites-based catalysts and their applications in HMF and FUR upgrading are identified.