Accelerated Solar-Driven Polyolefin Degradation via Self-Activated Hydroxy-Rich ZnInS.

Degradation of polyolefin (PE) plastic by a traditional chemical method requires a high pressure and a high temperature but generates complex products. Here, sulfur vacancy-rich ZnInS and hydroxy-rich ZnInS were rationally fabricated to realize photocatalytic degradation of PE in an aqueous solution under mild conditions. The results reveal that the optimized photocatalyst could degrade PE into CO and CO, and PE had a weight loss of 84.5% after reaction for 60 h. Systematic experiments confirm that the synergetic effect of hydroxyl groups and S vacancies contributes to improve the photocatalytic degradation properties of plastic wastes. In-depth investigation illustrates that the active radicals attack (h and •OH) weak spots (C-H and C-C bonds) of the PE chain to form CO, which is further selectively photoreduced to CO. Multimodule synergistic tandem catalysis can further improve the utilization value of plastic wastes; for example, product CO/CO in the plastic degradation process can be converted in situ into HCOOH by coupling with electrocatalytic technology.