Membrane technology is crucial in addressing water pollution challenges, particularly in removing dyes from wastewater. This study presents a novel approach to fabricating shear-aligned graphene oxide (GO) nanosheets incorporated polyvinylidene fluoride (PVDF) membranes for achieving exceptional dye rejection efficiency while maintaining high water flux. The membranes were prepared by dispersing graphene oxide within a PVDF matrix and subsequent subjection to shear alignment techniques. Shear and flow-induced alignment were explored to achieve precise and controlled alignment of graphene oxide flakes within the PVDF matrix. The resulting membranes exhibited enhanced structural integrity and optimized molecular packing of PVDF and GO, enabling them to selectively reject dyes while allowing efficient water permeation. The fabricated membranes were extensively characterized using appropriate testing methods. The results demonstrated that the shear-aligned GO sheets infused PVDF composite membranes exhibited outstanding dye rejection (96-99%) performance, surpassing conventional membranes while maintaining high water flux. This innovative membrane fabrication approach holds significant promise for advanced water treatment applications, offering a sustainable solution for selective dye removal and efficient water purification.
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http://dx.doi.org/10.1039/d4ra04147j | DOI Listing |
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January 2025
College of Material Science and Engineering, Hunan University, Changsha, Hunan, 410082, China.
Single-atom catalysts (SACs) with high activity and efficient atom utilization for oxygen reduction reactions (ORRs) are imperative for rechargeable Zinc-air batteries (ZABs). However, it is still a prominent challenge to construct a noble-metal-free SAC with low cost but high efficiency. Herein, a novel nitrogen-doped graphene (NrGO) based SAC, immobilized with atomically dispersed single cobalt (Co) atoms (Co-NrGO-SAC), is reported for ORRs.
View Article and Find Full Text PDFBioconjug Chem
January 2025
Department of Biochemistry, Faculty of Biological and Veterinary Sciences, Nicolaus Copernicus University in Torun, ul. Lwowska 1, 87-100 Torun, Poland.
l-Asparaginase (l-ASNase) catalyzes the hydrolysis of l-asparagine, leading to its depletion and subsequent effects on the cellular proliferation and survival. In contrast to normal cells, malignant cells that lack asparagine synthase are extremely susceptible to asparagine deficiency. l-ASNase has been successfully employed in treating pediatric leukemias and non-Hodgkin lymphomas; however, its usage in adult patients and other types of cancer is limited due to significant side effects and drug resistance.
View Article and Find Full Text PDFNanoscale
January 2025
Department of Chemistry, Indian Institute of Technology Palakkad, Palakkad, Kerala 678 557, India.
Chemotherapy is a crucial cancer treatment, but its effectiveness requires precise monitoring of drug concentrations in patients. This study introduces an innovative electrochemical strip sensor design to detect and continuously monitor methotrexate (MTX), a key chemotherapeutic drug. The sensor is crafted through an eco-friendly synthesis process that produces porous reduced graphene oxide (PrGO), which is then integrated with gold nanocomposites and polypyrrole (PPy) to boost the performance of a screen-printed carbon electrode (SPCE).
View Article and Find Full Text PDFACS Nano
January 2025
Key Laboratory of New Membrane Materials, Ministry of Industry and Information Technology, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China.
Thermally driven membrane desalination processes have garnered significant interest for their potential in the treatment of hypersaline wastewater. However, achieving high rejection rates for volatiles while maintaining a high water flux remains a considerable challenge. Herein, we propose a thermo-osmosis-evaporation (TOE) system that utilizes molecular intercalation-regulated graphene oxide (GO) as the thermo-osmotic selective permeation layer, positioned on a hydrophobic poly(vinylidene fluoride) fibrous membrane serving as the thermo-evaporation layer.
View Article and Find Full Text PDFPLoS One
January 2025
Key Laboratory of Clinical Evaluation Technology for Medical Device of Zhejiang Province, Department of Clinical Engineering and Material Supplies, The First Affiliated Hospital, Zhejiang University School of Medicine, Hangzhou, P.R. China.
The structural alterations in the constituent materials of nanocomposites such as graphene nanocomposites typically induce changes in their properties including mechanical, electrical, and optical properties. Therefore, by altering the preparation conditions of nanocomposites and investigating their responsiveness to basic biomolecules (such as proteins), it is possible to explore the application potentials of the composites and guide development of new nanocomposite preparation. In this study, different composites of graphene oxide and gold nanoparticles (AuNPs/GO) were obtained by varying the volumes of reducing agents used in the one-pot hydrothermal method.
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