Chemical Oxygen Demand (COD) is crucial for assessing water quality. Compared to traditional chemical detection methods, UV-vis spectroscopy for measuring COD offers advantages such as speed, reduced consumption of materials, and no secondary pollution. Considering the impact of suspended particles in water, this paper proposes an optimized boosting model based on a combination strategy for turbidity compensation, using absorption spectra obtained from reservoir water samples UV-vis. A self-attention mechanism is introduced into the radial basis function (RBF) network, resulting in a COD detection model based on the saRBF framework. This model facilitates comprehensive optimization of the entire process, from turbidity compensation of the original absorption spectrum to the subsequent COD prediction. Experimental results show that the proposed COD measurement model achieves a coefficient of determination of 0.9267, a root mean square error of 1.2669, and a mean absolute error of 1.0097, outperforming other COD measurement models. This work provides a new approach for turbidity compensation and COD detection research.
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http://dx.doi.org/10.1039/d4ay01441c | DOI Listing |
Appl Spectrosc
December 2024
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, USA.
Environmental fluorescence measurements sometimes use water Raman scattering as an internal standard to compensate for path length, lensing effects, and turbidity. Fluorescent dissolved organic matter (FDOM) in water may interfere strongly with the measurement of this reference. However, fluorescence in fluid solution is largely unpolarized, while the OH stretching Raman band of water is always strongly polarized.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2025
North China Sea Marine Technical Center, Ministry of Natural Resources, Qingdao 266033, China.
Turbidity interference in measurements can reduce the accuracy of fluorescence detection. Conventional turbidity compensation methods directly establish the relationship between turbidity value and fluorescence but cannot accurately characterize the complex interference of turbidity on fluorescence detection. This paper introduces a novel turbidity compensation technique that separates the interference caused by turbidity particles into scattering intensifying and scattering-absorption attenuating components and corrects them separately.
View Article and Find Full Text PDFEnviron Monit Assess
November 2024
UMR 5600 Environnement Ville Et Société, Université Jean Moulin Lyon 3, CNRS, 18 Rue Chevreul Lyon 7, Lyon, France.
This study presents the process of design and development of a low-cost turbidimeter for monitoring water quality, facilitating rigorous spatial-temporal variability analysis within large-scale hydrological systems. We propose a low-cost optical turbidimeter, modifying the existent SEN0189 turbidity sensor, Arduino boards, and additional sensors for temperature compensation. We compared a low-cost system with high-tech sensors, modifying the original low-cost SEN0189 probe for enhanced environmental performance.
View Article and Find Full Text PDFAnal Methods
September 2024
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350005, China.
Chemical Oxygen Demand (COD) is crucial for assessing water quality. Compared to traditional chemical detection methods, UV-vis spectroscopy for measuring COD offers advantages such as speed, reduced consumption of materials, and no secondary pollution. Considering the impact of suspended particles in water, this paper proposes an optimized boosting model based on a combination strategy for turbidity compensation, using absorption spectra obtained from reservoir water samples UV-vis.
View Article and Find Full Text PDFJ Environ Sci (China)
December 2024
Sustainable Infrastructure and Resource Management (SIRM), UniSA STEM, University of South Australia, Mawson Lakes, SA 5095, Australia.
The reliable application of field deployable fluorescent dissolved organic matter (fDOM) probes is hindered by several influencing factors which need to be compensated. This manuscript describes the corrections of temperature, pH, turbidity and inner filter effect on fluorescence signal of a commercial fDOM probe (fDOM). For this, Australian waters with wide ranging qualities were selected, e.
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