Insights into the formation of secondary organic aerosols from agricultural residue burning emissions: A review of chamber-based studies.

Organic aerosols (OA) are a significant component of fine particulate matter in the ambient air and are formed through primary and secondary processes. Primary organic aerosols (POA) are directly released from sources, while secondary organic aerosols (SOA) are formed through the oligomerization and/or oxidation of volatile organic compounds (VOCs) in the atmosphere. Recently, there has an increasing attention on the SOA budgets, their formation pathways, and photochemical evolution due to their impacts on climate and human health. Biomass burning (BB) is a significant source of OA, contributing around 5-30 % to the SOA burden globally. Agricultural residue burning (ARB) is a type of BB that contributes ∼10 % of total atmospheric OA mass worldwide, whereas it contributes higher in Asian regions like China and India. ARB emits a significant amount of air pollutants, including VOCs, into the atmosphere. However, there is inadequate information on the transformation of ARB emissions to SOA due to limited laboratory studies. The present review focuses on the formation mechanism of SOA from ARB emissions, summarizing the current state of the art about ARB precursors and their oxidation products from chamber-based studies, including measurement methods and analytical instrumentation. The review also discusses the role of different types of oxidants in OA mass enhancement, factors affecting the overall SOA yield, and the uncertainties involved in the process.